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The Volcan sulphur deposits were probably first recognized by Europeans in the 17th century. The native sulphur deposits were reportedly exploited in the 19th century and used to manufacture sulphuric acid. In 1988 a reserve estimate was published by the Chilean government organisation Centro de Investigaciones Metalurgicas y Mineras (CIMM) of Santiago in the Boletin Minero based on a CORFO report dated 1987. The reserve figure published for Volcan was 4.7 Mt at a grade of 40% sulphur

For quite some time, the gold potential of the Volcan area was considered to unfavourable due to the inferred high level and the young age of the mineralised system. However, in 1990, the property was optioned to Minera Homestake (Chile) Limitada who conducted a program of reconnaissance geology directed toward gold targets. Over period of three years, Homestake conducted 2,980 meters of reverse circulation drilling in addition to preliminary geological and geophysical surveys. Three target areas were identified including Main, Angelina Sur and Angelina Norte, however, in 1993, Homestake concluded that the project was not consistent with their exploration strategy and dropped the option.

In 1994, Compañia Minera Cameco (Chile) Ltda (Cameco), entered into an option agreement with the vendors and over the following 3 years conducted 3,984 metres of reverse circulation drilling and 3,293 metres of diamond drilling. The majority of the drilling was focused on the Cerro Dorado East zone where drilling and metallurgical testing were encouraging. Despite the success of the drilling program, Cameco management elected not to exercise the purchase option agreement.

 

   
 

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